Hi Brent.
The only places I've even seen Volatiles drop are either from Elemental mobs, mining (earth), fishing (water), and herbing (life). Running Vp on regular makes for easy farming of volatile Air, I've literally fished up volatile water (and no fish on the hook), and fire I've literally only seen from mobs or on the AH. Also, the mobs you can mine when doing the hyjal portion of the molten front dailys occasionally drop fire (The giants) but usually it's just vendor trash.
Good luck!
I'm way better at holding my liquor than a panda.
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