You can try thottbot, but I do not know of a website that does what your asking (though Im sure it exsits). Im sure you have already tried a google search so I wont mention that. However the best way, as well as, the way a majority of PvPers learned, is just to PvP, as much as possible.
Play with every class and learn what they do, this is important for rogues because they are such a knee jerk reaction class in pvp. Vs other classes that get a 1.5 second time frame to make decisions, rogues have between .2 seconds to 1 second to make decisions. They are also (feel free to lol at this) a cooldown based class, even in cata. So you have to make a decision in less than a second that will affect the outcome of games.
The best advice I can give you is to practice, practice, practice. And keep recuperate up in duels/BGs at all times


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