Quoted from this thread at Elitist Jerks:
Hit Caps
Single 2H or 1H WHITE...........164 (5% hit) - ?
w/Draenei.....................132 (4% hit) - ?
w/Precision...................99 (3% hit) - ?
w/Draen + Prec................66 (2% hit) - ?
->Single 2H or 1H YELLOW..........296 (9% hit)
w/Draenei.....................263 (8% hit)
w/Precision...................197 (6% hit)
w/Draen + Prec................164 (5% hit)
Dual Wield WHITE................919 (28% hit)
w/Draenei.....................886 (27% hit)
w/Precision...................820 (25% hit)
w/Draenei + Prec..............788 (24% hit)
Titan's Grip YELLOW.............460 (14% hit)
w/Draenei.....................427 (13% hit)
-> w/Precision...................361 (11% hit)
w/Draen + Prec................328 (10% hit)The data can be a little hard to understand so I bolded the important values for a raid boss.Expertise (dodge) cap.............214 (26 Exp)
+3 Racial.....................189 (23 Exp)
-> Strength of Arms 2/2..........181 (22 Exp)
+5 Racial.....................173 (21 Exp)
-> Vitality 3/3..................164 (20 Exp)
SoA & +3 Racial...............156 (19 Exp)
-> Weapon Mastery 2/2............148 (18 Exp)
SoA & +5 Racial...............140 (17 Exp)
Vit & +3 Racial...............140 (17 Exp)
Vit & +5 Racial...............123 (15 Exp)
WM & +3 Racial................123 (15 Exp)
SoA & WM......................115 (14 Exp)
WM & +5 Racial................107 (13 Exp)
SoA & WM & +3 Racial..........82 (10 Exp)
SoA & WM & +5 Racial..........66 (8 Exp)
Mobs can dodge from behind, but cannot parry from behind. As such, if you are DPSing you should be attacking from behind to prevent parry-haste and so you only need worry about removing the mob's chance to dodge.
A raid bosses dodge chance is believed to be 6.5%. A raid boss' parry chance is variable and ranges from about 10-15%.


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