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ideally we do it at 20% because we bring fury warriors who can put out stupid amounts of damage. but you definitely want to do it before 10%, because normally the last 10% doesn't benefit your mana based dps as much as they are mostly oom, and there's a chance he'll die before the end of bl/hero which is a waste, or you don't have all 10/25 people still alive by then, which again isn't beneficial.
My shaman's normally blow it around 60% but it really depends on the fight right? if there's a stage of weakness for the boss, you blow it then. If there's a stage that needs to be survived through, and can be cut down by burning em fast, you do it then as well. Its all situational. Just not at 100% and not at 10% is all I can give input to. Anything inbetween, I imagine is gonna be good, optimal timing can give you maybe as much as 5% more dps, but not by much.
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